Volume 7, Issue 2 (June 2020)                   J. Food Qual. Hazards Control 2020, 7(2): 75-83 | Back to browse issues page


XML Print


Download citation:
BibTeX | RIS | EndNote | Medlars | ProCite | Reference Manager | RefWorks
Send citation to:

Kumar R, Bhattacharya B, Agarwal T, Chakkaravarthi S. Trans Fatty Acid Analysis of Frying Oil Using ATR-FTIR Spectroscopy: A Study on Indian Traditional Snack Foods. J. Food Qual. Hazards Control 2020; 7 (2) :75-83
URL: http://jfqhc.ssu.ac.ir/article-1-592-en.html
Department of Basic and Applied Sciences, National Institute of Food Technology Entrepreneurship and Management, Kundli, Sonepat, Haryana, India , chakkaravarthi77@gmail.com
Abstract:   (2153 Views)
Background: Trans Fatty Acid (TFA) content in oil is an important quality parameter due to its adverse health effect. This study was aimed to examine the TFA content in the frying oil used by street food vendors in India for two traditional snack foods.
Methods: Totally, 143 oil samples were collected at different frying times (0, 2, and 4 h) from five different vendors for Samosa and Jalebi. TFA levels of the oil samples were analyzed by Attenuated Total Reflection-Fourier Transform Infrared Spectroscopy (ATR-FTIR). Statistical analyses were carried out using SPSS software version 23.0.
Results: ATR-FTIR spectra exhibited an increase in peak intensity at 966 cm-1 with different frying time in both frying oil samples, indicating the formation of TFA. The TFA content in oils fried at 4 h was significantly higher than the ones at 0 and 2 intervals. It was found that 3 out of 74 (4%) Samosa fried oils and 12 out of 69 (17.4%) Jalebi fried oils were over the maximum allowed regulatory limit of TFA (5%). Jalebi fried oils had significantly higher TFA content than Samosa fried oils.
Conclusion: The increase in frying time decreased the peroxide values and increased saturated fatty acids and TFA values of oils used for both food items. The local vendors and consumers should be educated by national authorities regarding health risk of TFA in street fried snacks.

DOI: 10.18502/jfqhc.7.2.2887
Full-Text [PDF 563 kb]   (973 Downloads)    
Type of Study: Original article | Subject: Special
Received: 19/05/12 | Accepted: 20/01/13 | Published: 20/06/18

References
1. Agrawal A., Gupta R., Varma K., Mathur B. (2008). High trans fatty acid content in common Indian fast foods. Nutrition and Food Science. 38: 564-569. [DOI: 10.1108/ 00346650810920178] [DOI:10.1108/00346650810920178]
2. Balaswamy K., Rao P.G.P., Prabhavathy M.B., Satyanarayana A. (2012). Application of annatto (Bixa orellena L.) dye formulations in Indian traditional sweetmeats: Jilebi and Jangri. Indian Journal of Traditional Knowledge. 11: 103-108.
3. Bhardwaj S., Passi S.J., Misra A. (2011). Overview of trans fatty acids: biochemistry and health effects. Diabetes and Metabolic Syndrome: Clinical Research and Reviews. 5: 161-164. [DOI: 10.1016/j.dsx.2012.03.002] [DOI:10.1016/j.dsx.2012.03.002] [PMID]
4. Choe E., Min D.B. (2007). Chemistry of deep-fat frying oils. Journal of Food Science. 72: 77-86. [DOI: 10.1111/j.1750-3841.2007.00352.x] [DOI:10.1111/j.1750-3841.2007.00352.x] [PMID]
5. Das A.K., Babylatha R., Pavithra A.S., Khatoon S. (2013). Thermal degradation of groundnut oil during continuous and intermittent frying. Journal of Food Science and Technology. 50: 1186-1192. [DOI: 10.1007/s13197-011-0452-7] [DOI:10.1007/s13197-011-0452-7] [PMID] [PMCID]
6. Debnath S., Rastogi N.K., Gopala Krishna A.G., Lokesh B.R. (2012). Effect of frying cycles on physical, chemical and heat transfer quality of rice bran oil during deep-fat frying of poori: an Indian traditional fried food. Food and Bioproducts Processing. 90: 249-256. [DOI: 10.1016/j.fbp.2011.05.001] [DOI:10.1016/j.fbp.2011.05.001]
7. Dias F.S.L., Passos M.E.A., Tavares do Carmo M.G., Lopes M.L.M., Valente Mesquita V.L. (2015). Fatty acid profile of biscuits and salty snacks consumed by Brazilian college students. Food Chemistry. 171: 351-355. [DOI: 10.1016/j. foodchem.2014.08.133] [DOI:10.1016/j.foodchem.2014.08.133] [PMID]
8. Fernández P.M., Juan S. (2000). Fatty acid composition of commercial Spanish fast food and snack food. Journal of Food Composition and Analysis. 13: 275-281. [DOI: 10.1006/ jfca.2000.0893] [DOI:10.1006/jfca.2000.0893]
9. Firestone D. (2007). Regulation of frying fat and oil. In: Erickson M. (Editor). Deep frying: chemistry, nutrition and practical applications. AOCS Press, Champaign. pp: 373-385. [DOI:10.1016/B978-1-893997-92-9.50027-X]
10. Galvín S., Guillén-Sans R., Galbis J.A., Guzmán-Chozas M. (2016). Trans fatty acids in two classes of reformulated "zero trans" Spanish margarines by use of second derivative ATR-FTIR spectroscopy. LWT-Food Science and Technology. 65: 1066-1071. [DOI: 10.1016/j.lwt.2015.09.047] [DOI:10.1016/j.lwt.2015.09.047]
11. Goburdhun D., Jhaumeer-Laulloo S.B., Musruck R. (2001). Evaluation of soybean oil quality during conventional frying by FTIR and some chemical indexes. International Journal of Food Sciences and Nutrition. 52: 31-42. [DOI: 10.1080/ 09637480020027183] [DOI:10.1080/09637480020027183] [PMID]
12. Gupta V., Downs S.M., Ghosh-Jerath S., Lock K., Singh A. (2016). Unhealthy fat in street and snack foods in low-socioeconomic settings in India: a case study of the food environments of rural villages and an urban slum. Journal of Nutrition Education and Behavior. 48: 269-279. [DOI: 10.1016/j. jneb.2015.11.006] [DOI:10.1016/j.jneb.2015.11.006] [PMID] [PMCID]
13. Hashim Z., Mad Zaki S.S.A., Muhamad I.I. (2017). Quality assessment of fried palm oils using fourier transform infrared spectroscopy and multivariate approach. Chemical Engineering Transactions. 56: 829-834. [DOI: 10.3303/ CET1756139]
14. Imathiu S. (2017). Street vended foods: potential for improving food and nutrition security or a risk factor for foodborne diseases in developing countries. Current Research in Nutrition and Food Science. 5: 55-65. [DOI: 10.12944/CRNFSJ.5.2.02] [DOI:10.12944/CRNFSJ.5.2.02]
15. Jha S.N., Jaiswal P., Borah A., Gautam A.K., Srivastava N. (2015). Detection and quantification of urea in milk using attenuated total reflectance-fourier transform infrared spectroscopy. Food and Bioprocess Technology. 8: 926-933. [DOI: 10.1007/ s11947-014-1455-y] [DOI:10.1007/s11947-014-1455-y]
16. Karn S., Abraham R.A., Ramakrishnan L. (2013). Assessment of trans fatty acid content in widely consumed snacks by gas chromatography in a developing country. Food and Nutrition Sciences. 4: 1281-1286. [DOI: 10.4236/fns.2013.412164] [DOI:10.4236/fns.2013.412164]
17. Karunathilaka S.R., Farris S., Mossoba M.M. (2018). Rapid prediction of low (<1%) trans fat content in edible oils and fast food lipid extracts by infrared spectroscopy and partial least squares regression. Journal of Food Science. 83: 2101-2108. [DOI: 10.1111/1750-3841.14281] [DOI:10.1111/1750-3841.14281] [PMID]
18. Ma J., Zhang H., Tuchiya T., Miao Y., Chen J.Y. (2014). Rapid determination of degradation of frying oil using near-infrared spectroscopy. Food Science and Technology Research. 20: 217-223. [DOI: 10.3136/fstr.20.217] [DOI:10.3136/fstr.20.217]
19. Maindola A. (2019). FSSAI aiming to reduce hydrogenated trans fats in Indian food to 2%. New Delhi, India. URL: https://www.fssai.gov.in/upload/media/FSSAI_News_Transfat_FNB_03_01_2019.pdf. Accessed 1 March 2019.
20. Marina A.M., Wan Rosli W.I., Noorhidayah M. (2013). Quantitative analysis of peroxide value in virgin coconut oil by ATR-FTIR spectroscopy. The Open Conference Proceedings Journal. 4: 53-56. [DOI: 10.2174/ 2210289201304020053] [DOI:10.2174/2210289201304020053]
21. Mariod A., Matthäus B., Eichner K., Hussein I.H. (2006). Frying quality and oxidative stability of two unconventional oils. Journal of American Oil Chemists' Society. 83: 529-538. [DOI: 10.1007/s11746-006-1236-5] [DOI:10.1007/s11746-006-1236-5]
22. Matthäus B. (2006). Utilization of high-oleic rapeseed oil for deep-fat frying of French fries compared to other commonly used edible oils. European Journal of Lipid Science and Technology. 108: 200-211. [DOI: 10.1002/ejlt.200500249] [DOI:10.1002/ejlt.200500249]
23. McCarthy J., Barr D., Sinclair A. (2008). Determination of trans fatty acid levels by FTIR in processed foods in Australia. Asia Pacific Journal of Clinical Nutrition. 17: 391-396.
24. Mishra R., Sharma H.K. (2014). Effect of frying conditions on the physico-chemical properties of rice bran oil and its blended oil. Journal of Food Science and Technology. 51: 1076-1084. [DOI: 10.1007/s13197-011-0602-y] [DOI:10.1007/s13197-011-0602-y] [PMID] [PMCID]
25. Mossoba M.M., Seiler A., Steinhart H., Kramer J.K.G., Rodrigues-Saona L., Griffith A.P., Pierceall R., Van De Voort F.R., Sedman J., Ismail A.A., Barr D., Da Costa Filho P.A., et al. (2011). Regulatory infrared spectroscopic method for the rapid determination of total isolated trans fat: a collaborative study. Journal of American Oil Chemists' Society. 88: 39-46. [DOI: 10.1007/s11746-010-1648-0] [DOI:10.1007/s11746-010-1648-0]
26. Mossoba M.M., Srigley C.T., Kramer J.K.G. (2015). Portable FTIR analyzers for the rapid determination of total trans fat. Lipid Technology. 27: 11-13. [DOI: 10.1002/lite.201400074] [DOI:10.1002/lite.201400074]
27. Mozaffarian D., Katan M.B., Ascherio A., Stampfer M.J., Willett W.C. (2006). Trans fatty acids and cardiovascular disease. The New England Journal of Medicine. 354: 1601-1613. [DOI: 10.1056/NEJMra054035] [DOI:10.1056/NEJMra054035] [PMID]
28. Normand L., Eskin N.A.M., Przybylski R. (2006). Comparison of the frying stability of regular and high-oleic acid sunflower oils. Journal of American Oil Chemists' Society. 83: 331-334. [DOI: 10.1007/s11746-006-1208-9] [DOI:10.1007/s11746-006-1208-9]
29. Poiana M.A. (2012). Enhancing oxidative stability of sunflower oil during convective and microwave heating using grape seed extract. International Journal of Molecular Sciences. 13: 9240-9259. [DOI: 10.3390/ijms13079240] [DOI:10.3390/ijms13079240] [PMID] [PMCID]
30. Poiana M.A., Alexa E., Munteanu M.F., Gligor R., Moigradean D., Mateescu C. (2015). Use of ATR-FTIR spectroscopy to detect the changes in extra virgin olive oil by adulteration with soybean oil and high temperature heat treatment. Open Chemistry. 13: 689-698. [DOI: 10.1515/chem-2015-0110] [DOI:10.1515/chem-2015-0110]
31. Raj T., Kar J.R., Singhal R.S. (2017). Development of par-fried frozen Samosas and evaluation of its post-storage finish frying and sensory quality. Journal of Food Processing and Preservation. 41: e13049. [DOI: 10.1111/jfpp.13049] [DOI:10.1111/jfpp.13049]
32. Saadeh C., Toufeili I., Zuheir Habbal M., Nasreddine L. (2015). Fatty acid composition including trans-fatty acids in selected cereal-based baked snacks from Lebanon. Journal of Food Composition and Analysis. 41: 81-85. [DOI: 10.1016/j.jfca. 2015.01.014] [DOI:10.1016/j.jfca.2015.01.014]
33. Sanibal E.A.A., Mancini Filho J. (2004). Perfil de ácidos graxos trans de óleo e gordura hidrogenada de soja no processo de fritura. Food Science and Technology. 24: 27-31. [Spanish with English abstract] [DOI: 10.1590/S0101-20612004000100006] [DOI:10.1590/S0101-20612004000100006]
34. Sayyad R. (2017). Effects of deep-fat frying process on the oil quality during French fries preparation. Journal of Food Science and Technology. 54: 2224-2229. [DOI: 10.1007/ s13197-017-2657-x] [DOI:10.1007/s13197-017-2657-x]
35. Sherazi S.T.H., Kandhro A., Mahesar S.A., Bhanger M.I., Talpur M.Y., Arain S. (2009). Application of transmission FT-IR spectroscopy for the trans fat determination in the industrially processed edible oils. Food Chemistry. 114: 323-327. [DOI: 10.1016/j.foodchem.2008.09.058] [DOI:10.1016/j.foodchem.2008.09.058]
36. Siddique B.M., Muhamad I.I., Ahmad A., Ayob A., Ibrahim M.H., Ak M.O. (2015). Effect of frying on the rheological and chemical properties of palm oil and its blends. Journal of Food Science and Technology. 52: 1444-1452. [DOI: 10.1007/ s13197-013-1124-6] [DOI:10.1007/s13197-013-1124-6] [PMID] [PMCID]
37. Uauy R., Aro A., Clarke R., Ghafoorunissa, L'Abbé M.R., Mozaffarian D., Skeaff C.M., Stender S., Tavella M. (2009). WHO scientific update on trans fatty acids: summary and conclusions. European Journal of Clinical Nutrition. 63: 68-75. [DOI: 10.1038/ejcn.2009.15] [DOI:10.1038/ejcn.2009.15]
38. Wang Y., Hui T., Zhang Y.W., Liu B., Wang F.L., Li J.K., Cui B.W., Guo X.Y., Peng Z.Q. (2015). Effects of frying conditions on the formation of heterocyclic amines and trans fatty acids in grass carp (Ctenopharyngodon idellus). Food Chemistry. 167: 251-257. [DOI: 10.1016/j.foodchem.2014. 06.109] [DOI:10.1016/j.foodchem.2014.06.109] [PMID]
39. Weisshaar R. (2014). Quality control of used deep-frying oils. European Journal of Lipid Science and Technology. 116: 716-722. [DOI: 10.1002/ejlt.201300269] [DOI:10.1002/ejlt.201300269]
40. Zahir E., Saeed R., Hameed M.A., Yousuf A. (2017). Study of physicochemical properties of edible oil and evaluation of frying oil quality by fourier transform-infrared (FT-IR) spectroscopy. Arabian Journal of Chemistry. 10: S3870-S3876. [DOI: 10.1016/j.arabjc.2014.05.025] [DOI:10.1016/j.arabjc.2014.05.025]

Add your comments about this article : Your username or Email:
CAPTCHA

Rights and permissions
Creative Commons License This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

© 2024 CC BY-NC 4.0 | Journal of food quality and hazards control

Designed & Developed by : Yektaweb